PROGRAMMA SCIENTIFICO
09.30-11.30 Registrazione dei partecipanti
11.30-12.00 Apertura del Congresso
Chairman: Prof. Michele Aresta
12.00-13.00 Plenary Lecture: Ugo Romano (ENI S.p.A.)
Nuovi materiali e tecnologie di processo per l'industria
energetica.
13.00-15.00 Pranzo presso l’Orto Botanico
Chairman: Prof. Ivano Bertini
15.00-16.00 Plenary Lecture: (medaglia Sacconi) E. Carmona (Univ.Siviglia)
Tautomeric equilibria in iridium carbenes.
16.00-16.30 Keynote: P. Stoppioni (Univ. Firenze)
Activation of white phosphorus in the presence of transition
metal fragments.
16.30-16.50 Intervallo
Chairman: Prof. Piero Zanello
Comunicazioni Orali
16.50-17.10 A. Romerosa
Synthesis and characterization of the new water soluble
ligand dmPTA and its ruthenium complexes
(dmPTA = N,N’-dimethyl-1,3,5-triaza-7-phosphaadamantane).
17.10-17.30 A. Macchioni
Combining diffusion NMR and conductometric measurements
to evaluate the hydrodynamic volume of ions and ion pairs.
17.30-17.50 D. Cauzzi
Rh(I) complexes of the zwitterionic ligand
EtNHC(S)Ph2P=NPPh2C(S)NEt. Coordinative versatility and
acid-base properties.
17.50-18.10 S. Gross
Functionalised inorganic metal oxoclusters as nanosized
building blocks for the development of inorganic-organic
hybrid materials.
18.10-18.30 I. Fenoglio
Surface hydrophobicity and free radical generation of carbon
nanotubes.
18.30-18.50 C. Di Valentin
Nature of impurity states in N-doped TiO2: theory and
experiment.
20.00 Cocktail presso l’Orto Botanico
Chairman: Prof. Fausto Calderazzo
09.00-10.00 Plenary Lecture: (Chini) R. D. Adams (Univ. South
Carolina)
New directions for hydrogen activation and catalytic
hydrogenations.
Comunicazioni Orali
10.00-10.20 S. Zacchini
High nuclearity nickel poly-carbide and poly-acetylide carbonyl
clusters.
10.20-10.40 R. Della Pergola
Fe-Cu carbide clusters and substitution of their labile halide
ligands.
10.40-11.00 F. Fabrizi de Biani
Ptn clusters as synthons for extended conducing systems: an
electrochemical, spectroelectrochemical and theoretical study.
11.00-11.20 Intervallo
Chairman: Prof. Maurizio Peruzzini
11.20-11.50 Keynote: C. Allevi (SARAS – Milano)
Role of inorganic chemistry in the oil refining industry: effect
of catalyst onhydroprocessing for environmental friendly
fuels.
11.50-12.50 Flash Presentation FP1-FP12
C. Femoni, M. C. Iapalucci, G. Longoni, S. Zacchini,
F. Kaswalder
Copolymerisation and condensation of metal carbonyl clusters
with diamino ligands.
F. Cesana, A. Caselli, E. Gallo, F. Ragaini, M. Sisti,
N. Casati,
P. Macchi, S. Cenini
Asymmetric cyclopropanation by copper(I) complexes based
on functionalized pyridine-containing macrocyclic ligands.
Y. Diaz Fernandez, C. Mangano, P. Pallavicini, L. Pasotti,
S. Patroni
How to easily tune the window position along the pH axis in
fluorescent micellar sensors for pH windows.
D. Zuccaccia, E. Foresti, S. Pettirossi, P. Sabatino,
C. Zuccaccia, A. Macchioni
From ion pairs to ion triples through a hydrogen bonding-
driven aggregative process.
S. Delsante, G. Borzone
Phase stability of Ti-Zn intermetallics.
D. Braga, F. Grepioni, E. Dichiarante, M. Lusi, M. Polito,
K. Rubini
Reversible solid-state reaction between 18-Crown[6] and K/Rb/Cs(H2PO4) and solid state transition phase of
18-Crown[6][M(HSO4)]•xH2O.
D. Rogolino, A. Bacchi, M. Carcelli, C. Compari, E. Fisicaro,
N. Neamati, G. Pelizzi,
M. Sechi
β-Diketo acid metal complexes as inhibitors of HIV Type 1
integrase.
C. Piangiolino, E. Gallo, A. Caselli, S. Fantauzzi, F. Ragaini,
S. Cenini
Synthesis of new heterocyclic compounds by N-aryl-2-
vinylaziridines rearrangements.
C. Cassino, A. Buico, F. Dondero, M. Grattarola, L. Vergani,
D. Osella
ESR analysis of the radical scavenging ability of fish and
molluscan metallothioneins.
A. Scano, M. Pilloni, G. Ennas, G. Marongiu, G. Paschina
Synthesis and characterization of nanocrystalline manganese
ferrite using water-in-oil microemulsion.
G. Tamasi, S. Defazio, R. Cini
Synthesis, Structure and Cytotoxic Activity for New
Copper(II)-Oxicam Compounds.
A. Gallo, L. Sordelli, G. Peli, L. Garlaschelli, R. Della Pergola,
V. Dal Santo, R. Psaro
Characterisation of supported Ir-Sn nanoparticles catalysts
for
dehydrogenation of propane.
12.50-14.00 Pranzo
14.00-15.00 Sessione Poster P1-P60
P01 S. Mazzega Sbovata, F. Bettio, C. Marzano, A. Tassan, R.
A. Michelin, R. Bertani.
Bis-amidine and bis-iminoether Pt(II) complexes: synthesis,
characterization and biological activity.
P02 R. Ostuni, N. Margiotta, N. Denora,V. Laquintana,
G. Trapani, G. Natile.
The Translocator Protein: a new Target for cisplatin
derivatives.
P03 S. Bonetti, E. Gabano, M. Ravera, D. Osella.
Synthesis and characterization of a bio-molecular probe for
technetium radio-diagnosis and rhenium radio-therapy.
P04 M. Ravera, G. Bagni, C. Cassino, D. Osella.
Analysis of the interaction between DNA and Pt(II)-drugs
using an electrochemical biosensor: the role of carbonate in
the platinum binding.
P05 B. Chiavarino, M. Crestoni, S. Fornarini, F. Lanucara,
J. Lamaire, P. Maître, D. Scuderi.
Spectroscopic properties of the naked ferric heme-NO+
complex.
P06 F. Turci, E. Gazzano, M. Tomatis, G. Lesci, N. Roveri,
D. Ghigo, B. Fubini.
The Peculiar Role of Isolated Iron Ions in the Reactivity and Cellular Toxicity of Synthetic Chrysotile Asbestos.
P07 M. Aresta, A. Dibenedetto, F. Nocito, C. Pastore.
Comparison of the behaviour of soluble and supported tin catalysts in the synthesis of dimethylcarbonate from methanol and carbon dioxide.
Polystyrene-grafted tin-metallorganic species.
P08 M. Saporita, G. Bottari, D. Drommi, G. Bruno, F. Faraone.
Behaviour of the [(η5-C5Me5)Ru(N-N*)(NCMe)]PF6
complexes
as catalyst precursors for enantioselective allylic
alkylation reactions.
P09 E. Gallo, M.G. Buonomenna, L. Viganò, F. Ragaini,
A. Caselli, S. Cenini, E. Drioli.
New Catalytic Ruthenium Porphyrin Polymeric Membranes for the Heterogeneous Aziridination of Styrenes.
P10 A. Caselli, F. de Baldironi, E. Gallo, F. Ragaini,
M.G. Buonomenna, S. Cenini, E. Drioli.
New Catalytic Membranes for Fine Chemicals Synthesis:
Cyclopropanations Catalyzed by Co(II)-Schiff Base Complexes.
P11 A. Del Zotto, W. Baratta, M. Ballico, P. Rigo.
[RuCl2(PPh3)(P-L-Pyr)] Complexes (L = Imine or Amine
Donor) as Efficient Catalysts in Transfer Hydrogenation of
Ketones.
P12 A. Del Zotto, F. Iogna Prat, W. Baratta, P. Rigo,
E. Zangrando.
Palladacyclic Complexes with Imine and Amine Ligands.
Efficient Catalysts for Cross-Coupling Reactions.
P13 C.R. Barone, S. de Pinto, L. Maresca, G. Natile.
Reactivity of Coordinated Ligands: Behaviour of Allyl Acetate
Linked to Platinum(II).
P14 L. Busetto, P. Natanti, S. Bordoni, S. Cerini, S. Zacchini.
Half-Sandwich cyclopentadienyl Iridium complexes bearing
pendant oxygen ligands.
P15 D. Donghi, D. Maggioni, T. Beringhelli, G. D’Alfonso.
1H, 19F, and 15N NMR study of the interaction between
bis(pentafluorophenyl)borinic acid and nitrogen bases.
P16 T. Spataro, I. Aiello, M. Ghedini.
Design, syntheses and characterization of new
cyclometallated nickel(II) complexes.
P17 D. Pietrangeli, A. Salvati, S. Ristori, G. Martini, A. Rosa,
G. Ricciardi.
Synthesis, liposome insertion, and cytotoxicity of a
poly-carboranylalkylthio-porphyrazine with potential in
multiple approach anticancer therapy.
P18 M.R. Chierotti, L. Garlaschelli, R. Gobetto, C. Nervi, G. Peli, A. Sironi, R. Della Pergola.
Unusual carbonyl chemical shift in an hexairidium carbonyl
cluster: a combined Solid State NMR and DFT approach.
P19 S. Di Tommaso, T. Marino, F. Rondinelli, N. Russo,
M. Toscano.
CO2 Activation by Nb+ and NbO+ in Gas Phase. A Case of
Two State Reactivity Process.
P20 M. Pizzotti, T. Morotti, F. Tessore, R. Ugo, F. De Angelis,
S. Fantacci,A. Sgamellotti.
A DFT, TDDFT and EFISH investigation on the second order
NLO response of push-pull porphinato complexes
(M = Zn, Ni). The role of the metal.
P21 G. Albertin, S. Antoniutti, M. Noé.
Mixed-Ligand Stannyl Complexes of Ruthenium and Osmium
with Polypyridine and Phosphites.
P22 G. Albertin, S. Antoniutti, G. Zanardo.
Preparation and Reactivity of Azocomplexes of Iridium(III).
P23 G. Barone, V. D’anna, F. Ferrante, G. La Manna,
G. Li Manni, D. Duca.
Hydrogen on palladium clusters: a quantum chemical study.
P24 A. Terenzi, G. Barone, G. Ruisi, A. Silvestri.
he interaction of native calf thymus DNA with
Fe(III)- dipyrido[3,2-a:2’,3’-c]phenazine chloride.
P25 G. Peli, P. Macchi, M. Daghetta, L. Garlaschelli, A. Sironi.
An unprecedented cyclic dimer containing two iridium
carbonyl cluster units: synthesis and solid state structure of
[Ir4(CO)10(DPPPENT)]2
(DPPPENT= 1,5-bis(diphenylphosphino)pentane).
P26 M. Corsini, C. Rosani, F. Laschi, L. Giovagnini, D. Fregona, P. Zanello.
Electrochemical and spectroelectrochemical characterization
of mononuclear copper(II)-dithiocarbamate complexes.
P27 C. Garino, R. Gobetto, C. Nervi, L. Salassa, E. Rosenberg, J. B. A. Ross, Xi Chu.
Ru(II)Terpyridine Complex: The Importance of Weak
Intermolecular Forces to Photophysical Properties.
P28 D. Donghi, M. Panigati, M. Mauro, G. D’Alfonso, P. Mussini, L. D’Alfonso , P. Mercandelli,
A. Sironi.
Photophysical, electrochemical and DFT studies of
luminescent dinuclear Re(I) compounds.
P29 S. Lanza, G. Tresoldi.
HCl exchange between tight ion pairs
{[Rh(2-phpy)2(H2R2-DTO)]+,(Cl-)} and their dehydrohalogenated
forms [Rh(2-phpy)2(HR2-DTO)].
P30 G. Colucci, L. Fabbrizzi, M. Garolfi, M. Licchelli.
Anion-promoted deprotonation processes in
urea-metallocyclam conjugates.
P31 L. Marchiò, M. Gennari, M. Lanfranchi, M.A. Pellinghelli.
Cu-thiolate cluster. A structural model for the Cu-thionein core.
P32 L. Busetto, F. Marchetti, M. Salmi, S. Zacchini, V. Zanotti.
Reactions at the bridging vinyliminium ligand in diiron
complexes.
P33 M. Gennari, L. Marchiò, M. Lanfranchi, M.A. Pellinghelli.
Cu(I) Complexes with New Heteroscorpionate N2SS’-Donor
Ligands. Biomimetics of Blu Copper Sites.
P34 V. M. Vecchio, M. Benedetti, D. Migoni, S.A. De Pascali,
A. Ciccarese, F. Capitelli, F.P. Fanizzi.
Stereospecific metal mediated ortho-alkylation of phenols.
P35 M. Pellei, S. Alidori, H. V. Rasik Dias, G. Gioia Lobbia,
G. Papini, C. Santini.
Small Scorpionates: Silver(I)-Organophosphane Complexes
with Trihydro(5-CF3-pyrazol-1-yl)borate Ligand.
P36 M. Pellei, S. Alidori, D. Colavito, V. Gandin, G. Gioia Lobbia, C. Marzano, G. Papini, C. Santini, F. Tisato.
Tris(hydroxymethyl)phosphine Copper(I) and Silver(I)
Complexes: Synthesis, Characterization and in Vitro
Antitumor Properties.
P37 F. Cocco, M.A. Cinellu, G. Minghetti, L. Maiore, S. Stoccoro, A. Zucca, M. Manassero.
New Gold Complexes with Nitrogen Ligands: Synthesis,
Reactivity and Structures.
P38 E. Rossi, V. Calabrese, E. Cariati, C. Dragonetti, S. Quici,
D. Roberto, E. Tordin, R. Ugo.
Cis-[Ir(CO)2 ClL] (L = Annine-type Ligand) Complexes as
New NLO-phores.
P39 F. Marchetti, C. Pettinari, R. Pettinari, C. Di Nicola,
A. Cerquetella, A. Cingolani, A.H. White, A.J.L. Pombeiro.
Areneruthenium(II) 4-Acyl-5-pyrazolonate Derivatives:
Coordination Chemistry, Redox Properties and Reactivity.
P40 L. Ambrosio, M.C. Aragoni, M. Arca, F.A. Devillanova,
M.B. Hursthouse, S.L. Huth, F.Isaia, V. Lippolis, G. Verani.
New Light Emitting bis(1,2dithiolene) Complexes
[M(Ar,Hedt)2]x- (M = Ni, Au, Cu; Ar,Hedt =
Aryl1,2ethylenedithiolato; Ar = Phenyl, Naphtyl, 1-Pyrenyl,
2-Cumarenyl; x = 0, 1, 2).
P41 G. Brancatelli, F. Nicolò, M. Saporita, G. Bruno, F. Faraone.
Structural determination of organometallic complexes of
Palladium and Rhodium, containing optically active ligands
used in asymmetric catalysis.
P42 G. Ruisia, M.A. Girasolo.
Organotin(IV) Adducts of 5,7-Diphenyl-1,2,4-triazolo[1,5-a]
pyrimidine and 5,7-Ditertbutyl-1,2,4-triazolo[1,5-a]
pyrimidine.
P43 M.A. Girasolo, S. Rubino, G. Ruisi, G. Stocco.
L-Arginine, Na-Boc-L-Arginine and L-Alanyl-L-Arginine
complexes of Organotin(IV) ions. Synthesis and structural
investigations.
P44 R. Macchi, E. Cariati, D. Marinotto, D. Roberto, R. Ugo,
R. Bozio, M. Cozzuol, D. Pedron.
Electric–Field Assisted Growth of Highly Oriented DAST
Nano–Crystals in Polymeric Matrix for Non Linear Optical
Application.
P45 D. Belli Dell’Amico, F. Marchetti, S. Ramello, S. Samaritani.
Simple preparations of Pd6Cl12, Pt6Cl12 and Catn[Pt2Cl8+n]
n= 1, 2 (Cat = TBA and/or PPN).
P46 G. Forte, A. Grassi, G. Marletta.
Molecular Modeling of Oligopeptide Adsorption onto
Functionalised Quartz Surfaces.
P47 G. Mazzone, I. Rivalta, N. Russo, E. Sicilia.
Theoretical investigation of CO adsorption on PdAu(100) and
PdAu(111) alloys.
P48 L. Barbieri, M. Cannio, A. Corradi, I. Lancellotti, C. Siligardi.
Chromium Based Glasses from the Recycling of Galvanic
Sludges.
P49 M.C. Paganini, S. Livraghi, A. Malgorzata Czoska,
E. Giamello, C. Di Valentin, E. Finazzi, G. Pacchioni.
TiO2 visible light sensitization by non metal elements doping.
P50 M. Beccari, S. Pomponio, R. Cappannelli, V. Di Castro.
Copper surface functionalization by aromatic thiol self-
assembled monolayers.
P51 C. Campione, F. Porta, Ž. Krpetić, P. Riani.
Preparation of Au@Lanthanide Oxide Nanoparticles.
P52 G. Tagliabue, S. Galli, N. Masciocchi, A. Sironi, W. Wang, M.A. Romero, J.A.R. Navarro.
Thermodiffractometric Studies on Functional Coordination
Networks Containing the Polytopic Pyrimidindicarboxylate
Ligand.
P53 G. Cacciamani, J. De Keyzerb, N. Dupinc, P. Wollants.
Thermodynamic modelling of the FeNiTi system using a 4-
sublattice model for the fcc and bcc phases.
P54 M.L. Bonardi.
The IUPAC Project: Terminology, quantities and units
concerning production and application of radionuclides in
radiopharmaceutical and radioanalytical chemistry.
P55 C. Zona, M.L. Bonardi, F. Groppi, E. Persico, E. Quartapelle.
A wet–chemistry method for the radiochemical separation of
radiorhenium from Cyclotron irradiated tungsten target.
P56 C. Zona, M.L. Bonardi, F. Groppi, L. Canella, M. Chinol.
Evaluation of the behaviour of the Sr–resin minicolumn: Is it
a 90Sr/90Y generator or a fast QC tool for 90Y solution?
P57 L. Belpassi, I. Infante, F. Tarantelli, L. Visscher,
A. Sgamellotti.
Comparative Study of Chemical Bonds in NgAuF and NgAu+
(Ng = Ar, Kr, Xe) with Four Component Relativistic Density
Functional and Coupled Cluster Methods.
P58 G. de Petris, M. Rosi, A. Troiani.
The SSOH and HSSO Radicals. An Experimental and
Theorical Study of [S2OH]0/+/- Species.
P59 I. Fenoglio, G. Greco, S .Livraghi, E. Giamello, G. Martra, B. Fubini, C. Albrecht,
R.P.F. Schino.
Non photocatalytic free radical generation at the surface of
TiO2 nanoparticles: possible role in cellular toxicity.
P60 E. Gabano, S. Bonetti, L. Gaviglio, M. Ravera, M. Gariboldi,
E. Monti, D. Osella.
Pt(IV) complexes as anticancer pro-drugs. Chairman: Prof. Renzo Cini
15.00-15.30 Keynote: C. Pettinari (Università di Camerino)
Synthetic and analytical strategies for the preparation and
characterization of new coordination polymers based on
N-donor ligands: perspectives and applications.
Comunicazioni Orali
15.30- 15.50 S. Fornarini
Naked models of compound I of heme enzymes.
15.50-16.10 P. Pallavicini
A fluorescent micellar lipophilicity-meter for carboxylates.
16.10-16.30 S. Caramori
Indirect electrochemical sensing of DNA hybridization based
on the catalytic oxidation of cobalt(II)
16.30-16.50 Intervallo
Chairman: Prof. Luigi Busetto
Comunicazioni Orali
16.50-17.10 A. Villa
Role of the protecting agent on catalytic behavior of gold
based catalyst.
17.10-17.30 C. Pirovano
Silica-supported catalysts that combine a grafted rhodium
complex and palladium nanoparticles: synergistic effect in
arenes hydrogenation.
17.30-17.50 M. Baldoni
Formation, structure and polymorphism of novel lowest-
dimensional AgI aggregates by encapsulation in carbon.
17.50-18.10 M. Giovannini
Cu-rich solid solutions in Yb-Cu-T (T=Au, Ag, Pd) ternary
systems: synthesis, structure and physical properties.
18.10-18.30 G. M. Lombardo
Integrated XRPD-MD study of thermal effects on mixed metal
(Cu/Zn/Al) layered double hydroxides (LDHs), precursors for
the OSRM reaction catalysts.
18.30-18.50 C. Zona
Radiochemical separation of radioastatine from cyclotron
irradiated bismuth target: two different approaches.
Chairman: Prof.ssa Gabriella Borzone
09.00-10.00 Plenary Lecture:
Stefan Kaskel (Tech. Univ. Dresden).
Porous inorganic materials - synthesis, characterization and
application.
Comunicazioni Orali
10.00-10.20 R. Scotti
Pure and mixed phase sol-gel prepared TiO2 for photocatalytic
purposes.
10.20-10.40 P. Zanello, S. Fedi, F. Laschi, B. Zhu, R.J. Angelici. Electrochemistry of the corannulene ruthenium(II)
sandwich complex [(η6-C6Me6)Ru(η6- C20H10)](SbF6)2.
10.40-11.00 E. Barea
Application of porous coordination polymers in adsorption of
gases of environmental interest.
11.00-11.20 Intervallo
Chairman: Prof.ssa Franca Morazzoni
11.20-11.50 Keynote: V. Buscaglia (IEI Genova)
Complex inorganic materials by nanoparticle assembly.
Comunicazioni Orali
11.50-12.10 D. Pucci
Intermolecular motifs in the construction of molecular
materials based on pentacoordinated gallium(III) complexes.
12.10-12.30 C. Dragonetti
Cyclometallated iridium(III) complexes with large second
order NLO response and photoluminescence properties.
12.30-12.50 M. R. Chierotti
Solid-State NMR and X-Ray Analysis of Solvent-Free Reaction
Products
12.50-14.00 Pranzo
14.00-15.00 Sessione Poster P61-P118
P61 M. Saladini, E. Ferrari, S. Lazzari, F. Pignedoli, F. Spagnolo.
Fe(III) containing complexes with b-diketo derivatives for the
treatment of iron deficiency
P62 M. Belicchi-Ferrari, F. Bisceglie, G. Pelosi , S. Pinelli,
P. Tarasconi.
Long-chain aliphatic thiosemicarbazones and their Ni(II)
complexes.
P63 M. Ballico, W. Baratta, A. Del Zotto, P. Rigo.
Reactivity of Ruthenium Amino-Alkoxides and their
Involvement in Hydrogen Transfer Treactions.
P64 M. Ballico, W. Baratta, A. Del Zotto, P. Rigo.
C-H Activation and C-C Double Bond Formation Reactions in
Iridium Ortho-methyl Phosphine Complexes.
P65 L. Prati, A. Gaiassi, A. Villa.
Aminoacids by direct selective oxidation of aminoalcohols.
P66 E. Moretti, L. Storaro, M. Lenarda, A. Talon.
Effect of the synthetic parameters on the textural and
catalytic properties of ordered mesoporous Cu-Ce-Al systems.
P67 C. Della Pina, E. Falletta, M. Rossi.
Selective aerobic oxidation of tertiary amines on gold catalysts.
P68 C. Della Pina, E. Falletta, M. Rossi, A. Sacco.
Active sites characterization of gold nanoparticles by selective
doping.
P69 P. Stoppioni, P. Barbaro, M. di Vaira, S. Seniori Costantini,
M. Peruzzini.
New advances in coordination and degradation of white
phosphorus promoted by transition metal-ligandsystems.
P70 L. Cherchi, L. Garlaschelli, A. Sironi, P. Macchi, A. Fumagalli.
Multivalent Metal Carbonyl Clusters.
P71 C. Rosani, P. Zanello, M. Corsini, L. Messori, A. Casini,
C. Gabbiani, P. Mura.
Electrochemical characterization of the interaction of 2-amino-
5-methylthiazolium [trans-bis(2-amino-5-methylthiazole)
tetrachlororuthenate(III)] and cytochrome c interaction.
P72 E. Lucenti, G. D'Alfonso, C.Dragonetti, D. Roberto,
A. Sironi, R. Ugo.
Nucleophilic attack of Me3SiONa and MeONa on rhenium
carbonyl complexes.
P73 E. Guido, G. D’Amico, A. Albinati, A. Romeo, R. Romeo.
Synchronized Fluxional Motion and Cyclometalation of Ligands
in Platinum(II) Complexes.
P74 A. Pasini, L. Rigamonti.
Cis Influence in trans-[Pt(PPh3)2XY] Complexes.
P75 F. Bertolotti, E. Sappa, A. Secco.
The reactions of Fe3(CO)12 with 2-methyl-3-butyn-2-ol and
3-pentyn-1-ol in CH3OH/KOH solution. The X-ray structure of
Fe2(CO)6(µ-CO)[HCC{=C(CH3)2}C(=O)OCH3].
P76 E. Alberti, G.A. Ardizzoia, S. Brenna, F. Castelli, S. Galli,
A. Maspero.
Synthesis and reactivity of new dithiophosphonic acids: a
combined single-crystal, powder diffraction and solid-state
NMR study.
P77 R. Della Pergola, A. Sironi, L. Garlaschelli, D. Strumolo,
C. Manassero, M.Manassero.
8th and 9th group mixed metal clusters substituted with
alkynes and their reactivity towards acids.
P78 M. M. Dell’Anna, D. Giardina Papa, P. Mastrorilli,
C. F. Nobile, M. Peruzzini, U. Englert.
Synthesis, characterization and reactivity of palladium(II) and
platinum(II) complexes bearing the air stable primary
phosphane (ferrocenylmethyl)phosphane.
P79 C. Femoni, B. T. Heaton, M.C. Iapalucci, J. A. Iggo,
G. Longoni, C. Tiozzo, S. Zacchini.
Synthesis and characterization of new Rh- and Sn-centred
and conjuncto rhodium carbonyl clusters.
P80 P. Zanello, S. Fedi, F. Laschi, B. Zhu, R.J. Angelici.
Electrochemistry of the corannulene ruthenium(II) sandwich
complex [(η6-C6Me6)Ru(η6-C20H10)](SbF6)2.
P81 R. Vivani, F. Costantino, M. Nocchetti, U. Costantino,
M. Sisani.
Hybrid Zr phosphonate fluoride structures with different
dimensionalities.
P82 N. Garino, R. Gobetto, M.R. Chierotti, A. Viale, D. Braga,
F. Grepioni, M. Polito.
Investigation of Cis-Trans Isomerization in Crystalline [(η5-
C5H5))Fe(μ-CO)(CO)]2 by Solid-State NMR.
P83 N. Galdi, L. Izzo, L. Oliva.
Asymmetric synthesis with a chiral ansa-zirconocene and
regiochemistry of the styrene insertion into the Zr-C bond.
P84 L. Busetto, M.C. Cassani, C. Femoni, R. Mazzoni.
Synthesis and structural diversity of N-heterocyclic carbene-
amine silver and rhodium complexes.
P85 S. Aime, A. Barge, A. Crivello, A. Deagostino, S. Geninatti
Crich, R. Gobetto, C. Nervi,
A. Toppino, P. Venturello.
Carborane compounds for BNCT-MRI applications: hunting the
selectivity toward tumor cells.
P86 E. Boccaleri, E. Diana, S. F. A. Kettle, E. Marchese,
P. L. Stanghellini.
Prussian Blue analogues: from different preparations,
different spectra.
P87 E. Diana, E. Boccaleri, S. F. A. Kettle, E. Marchese,
P. L. Stanghellini.
Kinematic and computational models for the interpretation of
vibrations in cyano- bridged complexes.
P88 A. Orbelli Biroli, M. Ronchi, M. Pizzotti, R. Ugo, E. Lucenti,
M. Cavazzini, S. Quici.
Synthesis, NLO and photoluminescent properties of
nanoorganized chromophores on tetracyclosiloxane rings.
P89 A. Burini, R. Galassi, D. Paglialunga, A. A. Mohamed,
Jose´-Ramo´n Gala´n Mascaro´s,
K. R. Dunbar,
J. P. Fackler, Jr.
Host-Guest Supramolecular Chloride Anion Complexation by
Cyclic Hexanuclear Copper(II) Pyrazolate.
P90 G. Ciancaleoni, D. Zuccaccia, E. Clot, A. Macchioni.
Self-aggregation of half-sandwich Ru(II) precatalysts for
transfer hydrogenation: from monomers to nanoaggregates.
P91 A. Bellusci, A. Crispini, M. Ghedini, D. Pucci, E. I. Szerb.
Silver(I) Complexes as Building Blocks for the Development of
New Supramolecular Structures.
P92 A. Bellusci, S. Bernardini, R. Bloise, A. Crispini, M. Ghedini,
D. Pucci, A. Valentini.
Coordination Chemistry and Biological Evaluation of Tropolone
based Bifunctional Zn(II) Complexes.
P93 A. Bellusci, A. Crispini, M. Ghedini, P. F. Liguori, F. Marchetti,
C. Pettinari, D. Pucci.
Synthesis and Characterization of New Multifunctional Zn(II)
Complexes.
P94 M. P. Donzello, E. Viola, C. Bergami, F. Monacelli, C. Rizzoli,
C. Ercolani.
Mono- and pentapalladated tetra -2,3-pyrazinophorphyrazines
as photosensitizers for the production of singlet oxygen.
P95 P. Mastrorilli, V. Gallo, C. F. Nobile, P. Braunstein,
U. Englert.
N-substituted bis(diphenylphosphanyl)amine ligands bearing
the thioether functional group: coordination modes in PtCo2
and PtMo2 based clusters.
P96 P. Tagliatesta, A. Lembo, A. Salvatori.
Synthesis and UV-Visible charcterization of a new covalently
linked porphyrin-[60]fullerene dyad.
P97 G. Giorgi, P. Belanzoni, G. F. Cerofolini, A. Sgamellotti.
On a metastable configuration at the hydrogenterminated
(100) Si surface.
P98 A. Rodríguez-Diéguez, M A. Palacios, A. Sironi E. Colacio.
2D Self-assembled bimetallic-tetrazolate networks: crystal
structure and magnetic properties of [Co0.5N0.5 (pmtz)2]
(pmtz=5-(pyrimidyl)tetrazolate).
P99 D. Maggioni, G. D’Alfonso, S. De Marco, F. Guizzardi,
M. Indrieri, E. Jacchetti, C. Lenardi,
G. Marinoni, P. Milani.
Preparation and characterization of sol-gel TiO2
nanostructured thin films for MDCK cells adhesion studies.
P100 A. Arrais, E. Boccaleri, P. L. Stanghellini, S. Avedano,
M. Botta, G. B. Giovenzana, S. Aime.
Simple synthetic strategies for the water-dispersion of single-
walled carbon nanotubes filled with Gd(III) cations: towards a
new class of efficient nanosized materials for MRI
applications.
P101 A. Corradi, A. M. Ferrari, C. Leonelli, A. Rizzuti.
Microwave assisted hydrothermal synthesis of monoazite
LaPO4 nanofibers.
P102 I. Corazzari, I. Fenoglio, I. Matekovits, S. Spriano, B. Fubini.
Mechanical properties and surface reactivity of hard metals
based on innovative cobalt-free matrixes.
P103 A. Testino, V. Buscaglia, M. D’Arienzo, R. Scotti,
F. Morazzoni.
Synthesis of nanoparticles from solution. Thermodynamic
and kinetic modelling.
P104 F. Morazzoni, R. Scotti, M. D'Arienzo, A. Testino.
Contribution of the "Operando" EPR spectroscopy to model
the sensing mechanism in metal-oxide based gas sensors.
P105 S. De Negri, A. Saccone, S. Delfino.
Phase relations in the Y-Cu-Mg system.
P106 L. Carlucci, G. Ciani, S. Maggini, D. M. Presepio.
Interpenetration vs. non-interpenetration in 3D MOFs: a
systematic investigation of [M(BIX)3]X2 species of pcu
topology.
P107 M. Nocchetti, U. Costantino, F. Montanari, P. Čapková.
Interlayer organization of benzoate anions into ZnAl-
hydrotalcite from experimental and molecular modelling data.
P108 V. De Grandi, V. Dal Santo, A. Gallo, M. Gatti, R. Psaro,
S. Recchia.
OM-CVD preparation of oxide supported Rh nanoparticles for
the partial oxidation of CH4
P109 S. Gross, F. Graziola, V. Di Noto, R. Di Maggio,
M. Sangermano.
Inorganic-organic hybrid materials based on covalent
incorporation of transition metal oxoclusters in polymers:
functional and structural properties.
P110 M. Scarpellini, E. Lucenti, V.Srdanov, A. Podesta, P. Milani,
D. Roberto.
Surface functionalization for optoelectronic applications.
P111 P. Riani, N. Parodi, S. Amore, R. Marazza, G. Borzone,
F. Nanni, G. Gusmano.
Thermodynamic Properties of the CuInSn lead free alloys.
P112 I. Venditti, V. Marcianò, I. Fratoddi, M. V. Russo.
Novel synthesis and characterization of poly-3-dimethylamine-
1-propyne nanobeads by modified emulsion polymerization
technique.
P113 R. Vitaliano, C. Battocchio, I. Venditti, I. Fratoddi,
P. Di Marco, L. Mareschi, V. Marcianò,
M. V. Russo.
Nanostructured polymetallaynes and related model
molecules: synthesis and characterization.
P114 F. Vitale, R. Vitaliano, C. Battocchio, I. Venditti, I. Fratoddi,
E. Piscopiello, L. Tapfer, M.V. Russo.
Novel functionalized Pd(II) organometallic model complexes
linked to gold nanoclusters
P115 R. Pievo, M. Gullotti, L. Santagostini, E. Monzani,
L. Casella.
Tyrosinase catalyzes asymmetric sulfoxidation.
P116 R.P. Bonomo, G. Tabbì, L. I. Vagliasindi.
Electrochemical studies of nitric oxide interaction with
copper(II) complexes of prion protein bis-octarepeat
fragments.
P117 F. Rosalbino, R. Carlini, R. Marazza, D. Mazzone, E. Puzo,
P. Riani, G. Zanicchi
Electrochemical Characterization of Lead-Free Sn-Ag-Cu
Solder Alloys
P118 F. De Angelis, S. Fantacci, A. Sgamellotti, D. Roberto,
R. Ugo
Spectroscopy and non-linear optical properties of nanoscale
systems: insight from TDDFT calculations.
Chairman: Prof. Roberto Gobetto
15.00-15.30 Keynote: (Miglior Tesi di Dottorato) M. Mannini
(Univ. Firenze)
Molecular magnetic materials on solid surfaces.
Comunicazioni Orali
15.30-15.50 C. Nervi
Electrochemical and spectroscopic properties of
cyclometalated iridium complexes with
1-Pyridylimidazo[1,5-α]Pyridine ligands.
15.50-16.10 S. Milione
Iron complexes of bidentate nitrogen donor ligands as
catalysts for atom transfer radical polymerization of styrene.
16.10-16.30 S. Stagni
Tetrazolates as conjugated bridges for Ir(III)-Ru(II) mixed
complexes.
16.30-16.50 Intervallo
Chairman: Prof. Giancarlo Pelizzi
Comunicazioni orali
16.50-17.10 V. Gallo
The Pt-O bond is the attack site in ractions of
[(Cy2PH)Pt(µ-PCy2)( κ2P,O-µ-Cy2PO)Pt(Cy2PH)] (Pt-Pt) with
nucleophiles or electrophiles.
17.10-17.30 Z. Krpetic
TEM and confocal microscopy investigations of the efficient
cellular uptake of gold nanoparticles into cancer cells.
17.30-17.50 A. Figini Albisetti
Structural and thermodiffractometric studies of coordination
polymers containing the ditopic bisimidazolylmethane ligand.
17.50-18.10 F. Costantino
New layered zirconium amino diphosphonates containing
carboxyalkyl and carboxyphenyl groups.
18.15-19.00 Assemblea Divisione
Chairman: Prof. Felice Faraone
09.00-10.00 Plenary Lecture: Luigi Monsù Scolaro (Univ. Messina)
Non-covalent self-assembled porphyrin systems.
Comunicazioni Orali
10.00-10.20 M. Tegoni
Structure and solution self-assembly equilibria of copper(II)
metallacrowns of aminohydroxamic acids.
10.20.10.40 P. Pelagatti
Mechanistic insights into acetophenone reduction catalyzed
by half-sandwich Ru(II) complexes containing 2-
(diphenylphosphino)aniline; a combined experimental and
theoretical study.
10.40-11.00 G. D’Amico
Isomerization of benzylplatinum(II) complexes: detection of
an elusive intermediate stabilized by an η2-Pt-C1-Cipso bond.
11.00-11.20 Intervallo
Chairman: prof. Antonio Tiripicchio
11.20-11.50 Keynote: E. Rizzarelli (Univ. Catania)
Metal ions and protein conformational diseases.
Comunicazioni Orali
11.50-12.10 M. Bruschi
Structural and electronic properties of the [FeFe]-
hydrogenase H-Cluster in different redox and protonation states. A DFT investigation.
12.10-12.30 G. Falini
Hydrothermal construction of hydroxyapatite architectures
from biogenic single crystals of calcite.
12.30-12.50 N. Re
A Density Functional Study of antitumor active platinum
complexes in trans geometry with a planar ligand.
12.50-13.10 L. Giovagnini
Thioredoxin redox system inhibition and mithochondrial
permeability increase by gold(III) dithiocarbamate complexes.
13.10-14.20 Pranzo
14.30-18.30 Gita sociale a Lodi
20.00 Cena Sociale
Chairman: Prof. Pierluigi Rigo
09.00-10.00 Plenary Lecture:(Premio Nasini)
Filippo De Angelis (CNR-ISTM Perugia)
Spectroscopy and non-linear optical properties of nanoscale
systems: Insights from theory
Comunicazioni Orali
10.00-10.20 E. Boccaleri
Preparation of water-dispersible paramagnetic nanoparticles
containing Gd3+ by encapsulation in chemically functionalised
carbon nanostructures.
10.20-10.40 S. A. De Pascali
Overcoming the cisplatin resistance: a promising strategy of
new β-diketonate Pt(II) complexes with sulfur ligand as
leaving group.
10.40-11.00 E. Diana
A DFT study of (C6H6)2Cr and (C6H6)Cr(CO)3: new insights
on bond and vibrational properties.
11.00-11.20 Intervallo
Chairman: Prof. Luigi Garlaschelli
11.20-11.50 Keynote: W. Baratta (Univ. Udine)
Ruthenium ampy complexes for fast hydrogen transfer
reactions.
11.50-12.10 S. Fantauzzi,
Activating effects on the aziridination of styrenes by aryl
azides catalyzed by Ru(TPP)CO. A mechanistic study.
12.10-12.30 S. Cerini
Silyl-mediated coordination of O-functionalized fluorenyl
ligands.
12.30-12.50 M. Crucianelli
Organometallic complexes as catalysts for oxidative
processes: the surprising case of methyltrioxorhenium(VII)
(MTO).
12.50-13.10 L. Rigamonti
Synthesis, characterisation and reactivity of mono, bi and
trinuclear copper(II) complexes with tridentate Schiff bases:
effect of substituents and reaction conditions.
13.10 Chiusura del Congresso
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Il congresso sarà focalizzato sulle seguenti tematiche di ricerca:
Chimica di coordinazione
Sintesi, caratterizzazione, reattività e studio delle proprietà chimico-fisiche di complessi di coordinazione.
Chimica Organometallica
Sintesi, caratterizzazione, reattività e studio delle proprietà chimico-fisiche di complessi organometallici.
Catalisi
Studio dei problemi connessi alla catalisi omogenea ed eterogenea con particolare riguardo alla comprensione del meccanismo di reazione e alla caratterizzazione dei catalizzatori.
Chimica Bioinorganica
Studio dei sistemi biologici legati alla chimica inorganica.
Chimica dello Stato Solido e dei Materiali
Sintesi, caratterizzazione e studio delle proprietà chimico-fisiche di solidi inorganici di potenziale utilizzo nel campo dei materiali.
Nanoscienze
Sintesi e caratterizzazione di materiali nanostrutturati a matrice inorganica.
Il congresso si articolerà in:
12 Sessioni per 45 Comunicazioni
Il programma potrà subire qualche modifica in funzione del numero dei contributi scientifici ricevuti.
6 Plenary Lecture
Che comprendono il Premio Nasini, la Medaglia Sacconi e la Chini Lecture.
Il pomeriggio nel quale sarà conferita la Medaglia Sacconi sarà dedicato ad un simposio legato all’argomento presentato dallo speaker.
7 Key note lectures
Una di queste è la conferenza “Miglior tesi di dottorato”
1 Sessione per 12 flash presentation
Illustrazione dei poster per non più di cinque minuti
2 Sessioni poster
7 Intervalli (coffee break)
4 Intervalli (pranzo)
Scarica il programma scientifico definitivo in formato word |
